Wagner model

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Template:For Wagner model is a rheological model developed for the prediction of the viscoelastic properties of polymers. It might be considered as a simplified practical form of the Bernstein-Kearsley-Zapas model. The model was developed by German rheologist Manfred Wagner.

For the isothermal conditions the model can be written as:

𝝈(t)=βˆ’p𝐈+βˆ«βˆ’βˆžtM(tβˆ’t)h(I1,I2)𝐁(t)dt

where:

  • 𝝈(t) is the Cauchy stress tensor as function of time t,
  • p is the pressure
  • 𝐈 is the unity tensor
  • M is the memory function showing, usually expressed as a sum of exponential terms for each mode of relaxation:
M(x)=βˆ‘k=1mgiΞΈiexp(βˆ’xΞΈi), where for each mode of the relaxation, gi is the relaxation modulus and ΞΈi is the relaxation time;
  • h(I1,I2) is the strain damping function that depends upon the first and second invariants of Finger tensor 𝐁.

The strain damping function is usually written as:

h(I1,I2)=mβˆ—exp(βˆ’n1I1βˆ’3)+(1βˆ’mβˆ—)exp(βˆ’n2I2βˆ’3),

The strain hardening function equal to one, then the deformation is small and approaching zero, then the deformations are large.

The Wagner equation can be used in the non-isothermal cases by applying time-temperature shift factor.

References

  • M.H. Wagner Rheologica Acta, v.15, 136 (1976)
  • M.H. Wagner Rheologica Acta, v.16, 43, (1977)
  • B. Fan, D. Kazmer, W. Bushko, Polymer Engineering and Science, v44, N4 (2004)