Umdeutung paper

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In the history of physics, "On the quantum-theoretical reinterpretation of kinematical and mechanical relationships" (Template:Langx), also known as the Umdeutung (reinterpretation) paper,^[1]^[2] was a breakthrough article in quantum mechanics written by Werner Heisenberg, which was published in Zeitschrift für Physik in July 1925.^[3]

In his article, Heisenberg described a new framework for quantum theory that was focused exclusively on observable parameters, parameters that could be measured in scientific experiments, such as transition probabilities or frequencies associated with quantum jumps in spectral lines. This contrasted with earlier quantum theories that focused on unobservable parameters, like the position or velocity of electrons in electron orbits. In contrast to other quantum theories, Heisenberg assumed that issues stemmed from the kinematics (how position and velocity were defined) in the old quantum theory, not classical equations of motion.

Mathematically, Heisenberg used two indices for his reinterpretation of position, corresponding to initial and final states of quantum jumps. In addition, Heisenberg introduced non-commutative operators in a new multiplication rule, i.e. generally $A B \neq B A$ for quantum quantities $A$ and $B$ . This insight would later become the basis for Heisenberg's uncertainty principle.^[4]Template:Reference page Heisenberg used his framework to successfully explain the energy levels of a one-dimensional anharmonic oscillator.^[5]Template:Rp

The Umdeutung paper was followed by another paper by Max Born and Pascual Jordan in 1925 that built on the Umdeutung paper's conceptual framework,^[6] and by the 'three-man paper' (Template:Langx) by Born, Heisenberg and Jordan in 1926.^[7]^[1]^[8] These articles described matrix mechanics that would come to substitute old quantum theory. It was the first mature mathematical formulation of quantum mechanics.^[9]

For his work on developing quantum mechanics, Heisenberg received the Nobel Prize in Physics in 1932.^[10]

Historical context

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In early 1924, a year before Heisenberg's paper was published, a few physicists were already calling for abandonment of unobservable quantities in electron orbits; for instance, Arnold Sommerfeld abandoned them in discussing complex spectral lines.^[11]

The general narrative surrounding the Umdeutung paper states that Heisenberg, then 23 years old, worked on the article whilst recovering from hay fever on the largely vegetation-free island of Heligoland for about 10 days after arriving on June 6, 1925, where he had a eureka moment that lead to mature quantum mechanics.^[12]^[13] However, this narrative has been criticised for stemming from Heisenberg's account in his 1969 to 1971 memoirs, where Heisenberg stated his book was written in broad historical terms without precise detail.^[14] It has been argued that Heisenberg's account is hard to reconcile with contemporary evidence and that the majority of the paper was likely written after Heisenberg's stay on Heligoland in the first weeks of July.^[1]

It has also been argued that the idea of a 'eureka' discovery conflicts with Heisenberg's frequent correspondence with Wolfgang Pauli on his paper that expressed uncertainty.^[14] When asked for his opinion of the manuscript, Pauli responded favorably, but Heisenberg said that he was still "very uncertain about it". After returning from Heligoland, Heisenberg would discuss exclusively with Pauli using letters, making Pauli the only person aware of the successes and failures of Heisenberg's quantum mechanics.^[15] In July 1925, he sent the manuscript to Max Born to review and decide whether to submit it for publication.^[15] The idealisation of Heisenberg's work as a 'eureka' breakthrough has also been seen as disproportional when compared to the work other physicists made at the same time.^[16]

In classical physics, the intensity of each frequency of light produced in a radiating system is equal to the square of the amplitude of the radiation at that frequency, so attention next fell on amplitudes. The classical equations that Heisenberg hoped to use to form quantum theoretical equations would first yield the amplitudes, and in classical physics one could compute the intensities simply by squaring the amplitudes. But Heisenberg saw that "the simplest and most natural assumption would be"^[17]Template:Rp to follow the lead provided by recent work in computing light dispersion done by Hans Kramers.^[18] The work he had done assisting Kramers in the previous year^[17]Template:Rp now gave him an important clue about how to model what happened to excited hydrogen gas when it radiated light and what happened when incoming radiation of one frequency excited atoms in a dispersive medium and then the energy delivered by the incoming light was re-radiatedTemplate:Snd sometimes at the original frequency but often at two lower frequencies the sum of which equalled the original frequency. According to their model, an electron that had been driven to a higher energy state by accepting the energy of an incoming photon might return in one step to its equilibrium position, re-radiating a photon of the same frequency, or it might return in more than one step, radiating one photon for each step in its return to its equilibrium state. Because of the way factors cancel out in deriving the new equation based on these considerations, the result turns out to be relatively simple.

Description

Heisenberg's reinterpretation of quantum theory

One of the key aspects of Heisenberg's paper in forming a new quantum theory was its deliberate choice to not utilise unobserved quantities such as the electron's position and period but only to utilise observable parameters like transition probabilities or spectral frequencies.^[17]^[19] Whilst this has been seen as one of the succeeding innovations of Heisenberg's paper in moving away from classical mechanics,^[20] others have viewed the correspondence principle, the idea that quantum systems will behave like classical systems in the classical limit, as the primary driver of Heisenberg's argument.^[21]^[22] His letter to Ralph Kronig one month before the publishing of the Umdeutung paper closely follows the same structure as the paper but emphasises the correspondence of the Fourier coefficients rather than the philosophical focus on observable quantities.^[23]

An electron falling from energy state 3 to energy state 2 (left) emits a photon. The wavelength is given by the Rydberg formula (middle). Calculating the wavelength for hydrogen energy levels, it correspond to a red photon (right). The important question was what will be the intensity of radiation in the spectrum at that wavelength?

Fourier reinterpretation

Classically, an electron's orbit in stationary state $n$ can be expressed as a Fourier series for some characteristic frequency $ω (n)$ $x = \sum_{α = - \infty}^{\infty} {\vec{X}}_{α} (n) e^{i α ω (n) t},$ where ${\vec{X}}_{- α} (n) = {\vec{X}}_{α}^{*} (n)$ to ensure that $x$ is real-valued ( ${\vec{X}}^{*}$ is the complex conjugate of $\vec{X}$ ).^[24]

Heisenberg reinterprets this equation in terms of quantum jumps from state $n$ to all other states $n - α$ ^[25]^[26] Template:Equation box 1 where $ω (n, n - α)$ represents the frequency of light emitted/absorbed and $\vec{X} (n, n - α)$ represents an intensity of the light from the jump, relating to the probability of it transitioning.

Heisenberg mentions that $ω (n, n - α)$ may be found using the Bohr model calculation of $ω (n, n - α) = \frac{1}{ℏ} [W (n) - W (n - α)]$ where $W (n)$ is the energy of a given stationary state $n$ .^[27]

A justification for Heisenberg's Fourier reinterpretation can be seen when comparing classical and quantum expressions for the orbital frequencies. Classically, using action-angle variables, it can be found that $α ω = lim_{ϵ \to 0} \frac{E (J + α ϵ) - E (J)}{ϵ}, α \in ℤ$ as $d E / d J = ω$ ; in the Bohr model, by contrast, it is found that $ω (n, n - α) = \frac{E (n ℏ) - E ((n - α) ℏ)}{ℏ}, (E (J) = E (n ℏ)) .$ Using the correspondence principle $ω = \frac{d E}{d J} \to \frac{Δ E}{Δ J}$ it can be found $(n - (n - α)) ω = α ω (n) \approx \frac{E (n ℏ) - E ((n - α) ℏ)}{ℏ} = ω (n, n - α), | α - n | ≪ α .$ using $J = n ℏ$ from the old quantum theory.^[28] This correspondence between $ω (n, n - α)$ and $α ω (n)$ also suggests a correspondence between the intensities $\vec{X} (n, n - α)$ and ${\vec{X}}_{α} (n)$ in the connection $x = \sum_{α = - \infty}^{\infty} {\vec{X}}_{α} (n) e^{i α ω (n) t} ⟷ x = \sum_{α = - \infty}^{\infty} \vec{X} (n, n - α) e^{i ω (n, n - α) t} .$

This Fourier reinterpretation was also justified in Heisenberg's view so that the electron in its periodic motion, which the Bohr model predicted, would not have a single characteristic radiation frequency $ω (n)$ , corresponding to the frequency of the electron's periodic motion, in stationary state $n$ that had never been experimentally measured. Under Heisenberg's reinterpretation, the motion of the electron would only have the experimentally observed spectral frequencies $ω (n, n - α)$ as components of its periodic motion. Heisenberg notes, however, that by the publishing of the paper that the electronic orbit was abandoned as physically meaningful.^[29]

Non-commutative multiplication rule

Heisenberg uses the Rydberg–Ritz combination principle as a fundamental part of how frequencies should behave in his quantum theory. Rather than the classical rule $ω (n, α) + ω (n, β) = ω (n, α + β),$ where classically $ω (n, α) = α ω (n)$ , Heisenberg writes out the Ritz combination principle $ω (n, n - α) + ω (n - α, n - β) = ω (n, n - β) .$ .^[30]

Classically, multiplying two position Fourier series together forms a new Fourier series: $\sum_{τ} a_{τ} e^{i ω τ t} \times \sum_{τ} b_{τ} e^{i ω τ t} = \sum_{τ} c_{τ} e^{i ω τ t}$ where $c_{τ} = \sum_{τ^{'} + τ^{″} = τ} a_{τ^{'}} b_{τ^{″}} .$ ^[31]

Heisenberg analogised from this classical case that multiplying two quantum series should give another quantum series of the same form. In other words, Heisenberg finds that if a quantum series may be written $x = \sum_{α = - \infty}^{\infty} \vec{X} (n, n - α) e^{i ω (n, n - α) t},$ then $x^{2} = \sum_{β = - \infty}^{\infty} \vec{B} (n, n - β) e^{i ω (n, n - β) t} .$

Whilst a normal multiplication would not work to form a new quantum series, Heisenberg deliberately reinterprets multiplication to be now following the new quantum multiplication rule $\vec{B} (n, n - β) = \sum_{α} \vec{X} (n, n - α) \times \vec{X} (n - α, n - β) .$ ^[1]Template:Rp ^[23]

This is so that $e^{i ω (n, n - α) t} \times e^{i ω (n - α, n - β) t} = e^{i t (ω (n, n - α) + ω (n - α, n - β))} = e^{i t ω (n, n - β)}$ using the earlier Rydberg-Ritz Combination Rule $ω (n, n - α) + ω (n - α, n - β) = ω (n, n - β)$ so that all the frequencies $ω (n, n - β)$ are correct for the new series.^[22]

Generalizing from the earlier multiplication case of $x^{2}$ , Heisenberg wrote out his new, non-commutative multiplication rule that is the quantum mechanical analog for the classical computation of intensities:^[17]Template:Rp^[32]Template:Rp^[25]Template:Equation box 1 There will potentially be an infinite series of $\vec{A}$ terms and their matching $\vec{B}$ terms. Each of these multiplications has as its factors two measurements that pertain to sequential downward transitions between energy states of an electron. This type of rule differentiates matrix mechanics from the kind of physics familiar in everyday life because the important values are where (in what energy state or "orbital") the electron begins and in what energy state it ends, not what the electron is doing while in one or another state.

If $\vec{A}$ and $\vec{B}$ both refer to lists of amplitudes of quantum transitions, for instance, the calculation proceeds as follows:

Multiply the frequency for a change of energy from state $n$ to state $n - a$ by the frequency for a change of energy from state $n - a$ to state $n - b$ , and to that add the product found by multiplying the frequency for a change of energy from state $n - a$ to state $n - b$ by the frequency for a change of energy from state $n - b$ to state $n - c$ , and so forth. Symbolically, that is:

f (n, n - a) f (n - a, n - b) + f (n - a, n - b) f (n - b, n - c) + \dots

(According to the convention used, $n - a$ represents a higher energy state than $n$ , so a transition from $n$ to $n - a$ would indicate that an electron has accepted energy from an incoming photon and has risen to a higher orbital, while a transition from $n - a$ to $n$ would represent an electron falling to a lower orbital and emitting a photon.)

Heisenberg originally devised this equation to enable himself to multiply two measurements of the same kind (amplitudes), so it happened not to matter in which order they were multiplied. Heisenberg noticed, however that if he tried to use the same schema to multiply two variables, such as momentum, $p$ , and displacement, $q$ , then "a significant difficulty arises".^[17]Template:Rp It turns out that multiplying a matrix of $p$ by a matrix of $q$ gives a different result from multiplying a matrix of $q$ by a matrix of $p$ , with their difference being $i ℏ$ where $ℏ$ is the reduced Planck constant.

Motion

Heisenberg also notes that, in the old quantum theory, the observable quantities are solved from Newton's second law $\ddot{x} + f (x) = 0$ and the Wilson–Sommerfeld quantisation rule $\oint p d q = \oint m \dot{x} d x = \oint m {\dot{x}}^{2} d t = J = n h,$ where $f (x)$ is the force per unit mass function, where Heisenberg makes the assumption that, with his new Fourier reinterpretation of $x$ , the same Newtonian equations may be used to solve for observable quantities.^[22]

The idea that these same classical equations may continue to be used in quantum mechanics has been viewed as one of the most important ideas of Heisenberg's paper.^[33]

Quantisation

As a part of Heisenberg's justification for a theory of mechanics that is only reliant on the intensities and frequencies that are measurable, Heisenberg derives the Thomas-Reiche-Kuhn sum rule found from studying dispersion^[27]Template:Equation box 1for $x = \sum_{α = - \infty}^{\infty} a (n, n - α) e^{i ω (n, n - α) t}$ . ^[22]

Quantum anharmonic oscillator

Heisenberg additionally studies the energy levels of the anharmonic oscillator described by $\ddot{x} + ω_{0}^{2} x + λ x^{2} = 0$ , as the conceptually more simple harmonic oscillator would not have required his new multiplication rule.^[34] Whereas under a classical consideration he finds that $E_{n} = n ℏ ω_{0}$ , but under a quantum consideration using the theory developed in his paper, up to order $λ^{2}$ , he finds that $E_{n} = ℏ ω_{0} (n + \frac{1}{2}),$ explaining the existence of zero-point energy that had already been inferred by Robert S. Mulliken from spectroscopic experiments just six months prior.^[35]^[36]Template:Rp The lack of dependence on $λ$ made the equation written allowed to be used for the energy levels of the harmonic oscillator ( $λ = 0$ ) as well. Heisenberg would also extend this equation to the electron rotating at angular frequency $ω$ around the nucleus with moment of inertia $I = m a^{2}$ to find^[34] $ω_{n, n - 1} = \frac{h}{2 π m a^{2}} n$ and for the energy $W$ $W = \frac{h^{2}}{8 π^{2} m a^{2}} (n^{2} + n + \frac{1}{2})$ in agreement with experimental observations on the cyanide spectroscopic bands by Adolf Kratzer that introduced half-integral quantum numbers.^[24]

In addition, Heisenberg showed that the conservation of energy was supported by his theory.^[37]Template:Cn

Legacy

Development of matrix mechanics

Visible spectrum of hydrogen.

The one thing that people at that time most wanted to understand about hydrogen radiation was how to predict or account for the intensities of the lines in its spectrum. Although Heisenberg did not know it at the time, the general format he worked out to express his new way of working with quantum theoretical calculations can serve as a recipe for two matrices and how to multiply them.^[17]Template:Rp

The Umdeutung paper does not mention matrices. Heisenberg's great advance was the "scheme which was capable in principle of determining uniquely the relevant physical qualities (transition frequencies and amplitudes)"^[32]Template:Rp of hydrogen radiation.

After Heisenberg wrote the Umdeutung paper, he turned it over to one of his senior colleagues for any needed corrections and went on vacation. Max Born puzzled over the equations and the non-commuting equations that Heisenberg had found troublesome and disturbing. After several days he realized that these equations amounted to directions for writing out matrices.^[38]

By consideration of ... examples. .. [Heisenberg] found this rule ... This was in the summer of 1925. Heisenberg ... took leave of absence ... and handed over his paper to me for publication ... Heisenberg's rule of multiplication left me no peace, and after a week of intensive thought and trial, I suddenly remembered an algebraic theory....Such quadratic arrays are quite familiar to mathematicians and are called matrices, in association with a definite rule of multiplication. I applied this rule to Heisenberg's quantum condition and found that it agreed for the diagonal elements. It was easy to guess what the remaining elements must be, namely, null; and immediately there stood before me the strange formula $Q P - P Q = \frac{i h}{2 π}$

This equation is now called the canonical commutation relation, where the symbol $Q$ is the matrix for displacement, $P$ is the matrix for momentum, Template:Mvar stands for the square root of negative one, and Template:Mvar is the Planck constant.^[39]^[32]Template:Rp

Born discovered this equation by taking $Q_{n n^{'}} = a (n, n^{'}) e^{i ω (n, n^{'}) t}$ $P_{n n^{'}} = m \frac{d Q_{n n^{'}}}{d t} = i m ω (n, n^{'}) a (n, n^{'}) e^{i ω (n, n^{'}) t},$ which allowed him to simplify Heisenberg's complicated quantisation condition^[40] $h = 2 π m \sum_{α = - \infty}^{\infty} {| a (n, n + α) |^{2} ω (n, n + α) - | a (n, n - α) |^{2} ω (n, n - α)}$ $⟹ h = 2 π i \sum_{n^{'} = - \infty}^{\infty} (P_{n n^{'}} Q_{n^{'} n} - Q_{n n^{'}} P_{n^{'} n})$ $⟹ \frac{h}{2 π i} = \sum_{n^{'} = - \infty}^{\infty} (P_{n n^{'}} Q_{n^{'} n} - Q_{n n^{'}} P_{n^{'} n}),$ where he was able to recognise the multiplication of the components of $P$ and $Q$ surmounted to matrix multiplication.^[15]

When Born read the article, he recognized the formulation as one which could be transcribed and extended to the systematic language of matrices. Born, with the help of his assistant and former student Pascual Jordan, began immediately to make the transcription into pure matrix algebra and extension, and they submitted their results for publication; their manuscript was received for publication just 60 days after Heisenberg’s article.^[6] A follow-on article by all three authors extending the theory to multiple dimensions was submitted for publication before the end of the year.^[7]

Paul Dirac, who had received a proof copy in August 1925, realized that the non-commutative law had not been fully developed, and he produced an algebraic formulation to express the same results in more logical form.^[41] His insight led to new and productive directions in developing quantum mechanics.^[42]

During a conference about his new quantum mechanics at University of Berlin in 1926, Heisenberg explained that his construction of a theory solely from observable quantities followed the spirit of special relativity. In his auto-biography Physics and Beyond, Heisenberg says that after the conference Albert Einstein criticized this approach, arguing that no theory can be built from pure observation, since the elements that can be observed already depends on the theoretical assumptions.^[37]

"Magical paper"

Steven Weinberg would in 1993 refer to Heisenberg's paper as "pure magic" due to Heisenberg's lack of written motivation that he takes in justifying each mathematical step, leaving the reader "mystified" despite the successful predictions of Heisenberg's framework.^[43] A number of attempts have been made to explain his paper more accessibly.^[3]

Hundredth anniversary

Template:Main UNESCO celebrated the 100th anniversary of the publication of Heisenberg's paper by pronouncing 2025 as an observance year on quantum science and technology.^[44]

References

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Umdeutung paper

Contents

Historical context

Description