Griffiths inequality

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Template:Short description In statistical mechanics, the Griffiths inequality, sometimes also called Griffiths–Kelly–Sherman inequality or GKS inequality, named after Robert B. Griffiths, is a correlation inequality for ferromagnetic spin systems. Informally, it says that in ferromagnetic spin systems, if the 'a-priori distribution' of the spin is invariant under spin flipping, the correlation of any monomial of the spins is non-negative; and the two point correlation of two monomial of the spins is non-negative.

The inequality was proved by Griffiths for Ising ferromagnets with two-body interactions,[1] then generalised by Kelly and Sherman to interactions involving an arbitrary number of spins,[2] and then by Griffiths to systems with arbitrary spins.[3] A more general formulation was given by Ginibre,[4] and is now called the Ginibre inequality.

Definitions

Let σ={σj}j∈Λ be a configuration of (continuous or discrete) spins on a lattice Λ. If A⊂Λ is a list of lattice sites, possibly with duplicates, let σA=∏j∈Aσj be the product of the spins in A.

Assign an a-priori measure dμ(σ) on the spins; let H be an energy functional of the form

H(σ)=−∑AJAσA,

where the sum is over lists of sites A, and let

Z=∫dμ(σ)e−H(σ)

be the partition function. As usual,

⟨f⟩=1Z∫dμ(σ)f(σ)e−H(σ)

stands for the ensemble average.

The system is called ferromagnetic if, for any list of sites A, JA≥0. The system is called invariant under spin flipping if, for any j in Λ, the measure μ is preserved under the sign flipping map σ→τ, where

τk={σk,k≠j,−σk,k=j.

Statement of inequalities

First Griffiths inequality

In a ferromagnetic spin system which is invariant under spin flipping,

⟨σA⟩≥0

for any list of spins A.

Second Griffiths inequality

In a ferromagnetic spin system which is invariant under spin flipping,

⟨σAσB⟩≥⟨σA⟩⟨σB⟩

for any lists of spins A and B.

The first inequality is a special case of the second one, corresponding to B = ∅.

Proof

Observe that the partition function is non-negative by definition.

Proof of first inequality: Expand

e−H(σ)=∏B∑k≥0JBkσBkk!=∑{kC}C∏BJBkBσBkBkB!,

then

Z⟨σA⟩=∫dμ(σ)σAe−H(σ)=∑{kC}C∏BJBkBkB!∫dμ(σ)σAσBkB=∑{kC}C∏BJBkBkB!∫dμ(σ)∏j∈ΛσjnA(j)+kBnB(j),

where nA(j) stands for the number of times that j appears in A. Now, by invariance under spin flipping,

∫dμ(σ)∏jσjn(j)=0

if at least one n(j) is odd, and the same expression is obviously non-negative for even values of n. Therefore, Z⟨σA⟩≥0, hence also ⟨σA⟩≥0.

Proof of second inequality. For the second Griffiths inequality, double the random variable, i.e. consider a second copy of the spin, σ′, with the same distribution of σ. Then

⟨σAσB⟩−⟨σA⟩⟨σB⟩=⟨⟨σA(σB−σ'B)⟩⟩.

Introduce the new variables

σj=τj+τj′,σ'j=τj−τj′.

The doubled system ⟨⟨⋅⟩⟩ is ferromagnetic in τ,τ′ because −H(σ)−H(σ′) is a polynomial in τ,τ′ with positive coefficients

∑AJA(σA+σ'A)=∑AJA∑X⊂A[1+(−1)|X|]τA∖Xτ'X

Besides the measure on τ,τ′ is invariant under spin flipping because dμ(σ)dμ(σ′) is. Finally the monomials σA, σB−σ'B are polynomials in τ,τ′ with positive coefficients

σA=∑X⊂AτA∖Xτ'X,σB−σ'B=∑X⊂B[1−(−1)|X|]τB∖Xτ'X.

The first Griffiths inequality applied to ⟨⟨σA(σB−σ'B)⟩⟩ gives the result.

More details are in [5] and.[6]

Extension: Ginibre inequality

The Ginibre inequality is an extension, found by Jean Ginibre,[4] of the Griffiths inequality.

Formulation

Let (Γ, μ) be a probability space. For functions f, h on Γ, denote

⟨f⟩h=∫f(x)e−h(x)dμ(x)/∫e−h(x)dμ(x).

Let A be a set of real functions on Γ such that. for every f1,f2,...,fn in A, and for any choice of signs ±,

∬dμ(x)dμ(y)∏j=1n(fj(x)±fj(y))≥0.

Then, for any f,g,−h in the convex cone generated by A,

⟨fg⟩h−⟨f⟩h⟨g⟩h≥0.

Proof

Let

Zh=∫e−h(x)dμ(x).

Then

Zh2(⟨fg⟩h−⟨f⟩h⟨g⟩h)=∬dμ(x)dμ(y)f(x)(g(x)−g(y))e−h(x)−h(y)=∑k=0∞∬dμ(x)dμ(y)f(x)(g(x)−g(y))(−h(x)−h(y))kk!.

Now the inequality follows from the assumption and from the identity

f(x)=12(f(x)+f(y))+12(f(x)−f(y)).

Examples

Applications

  • The thermodynamic limit of the correlations of the ferromagnetic Ising model (with non-negative external field h and free boundary conditions) exists.
This is because increasing the volume is the same as switching on new couplings JB for a certain subset B. By the second Griffiths inequality
∂∂JB⟨σA⟩=⟨σAσB⟩−⟨σA⟩⟨σB⟩≥0
Hence ⟨σA⟩ is monotonically increasing with the volume; then it converges since it is bounded by 1.
  • The one-dimensional, ferromagnetic Ising model with interactions Jx,y∼|x−y|−α displays a phase transition if 1<α<2.
This property can be shown in a hierarchical approximation, that differs from the full model by the absence of some interactions: arguing as above with the second Griffiths inequality, the results carries over the full model.[7]
  • The Ginibre inequality provides the existence of the thermodynamic limit for the free energy and spin correlations for the two-dimensional classical XY model.[4] Besides, through Ginibre inequality, Kunz and Pfister proved the presence of a phase transition for the ferromagnetic XY model with interaction Jx,y∼|x−y|−α if 2<α<4.
  • Aizenman and Simon[8] used the Ginibre inequality to prove that the two point spin correlation of the ferromagnetic classical XY model in dimension D, coupling J>0 and inverse temperature β is dominated by (i.e. has upper bound given by) the two point correlation of the ferromagnetic Ising model in dimension D, coupling J>0, and inverse temperature β/2
⟨𝐬i⋅𝐬j⟩J,2β≤⟨σiσj⟩J,β
Hence the critical β of the XY model cannot be smaller than the double of the critical β of the Ising model
βcXY≥2βcIs;
in dimension D = 2 and coupling J = 1, this gives
βcXY≥ln⁡(1+2)≈0.88.
  • There exists a version of the Ginibre inequality for the Coulomb gas that implies the existence of thermodynamic limit of correlations.[9]
  • Other applications (phase transitions in spin systems, XY model, XYZ quantum chain) are reviewed in.[10]

References

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