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  • | ImageFile = Tris(trimethylsilyl)amin Strukturformel.svg | PIN = 1,1,1-Trimethyl-''N'',''N''-bis(trimethylsilyl)silanamine ...
    13 KB (1,771 words) - 01:25, 18 March 2023
  • ...nd thus can be used for alpha-[[hydroxylation]] of [[carbonyl]]-containing compounds.<ref>{{Cite journal | doi = 10.15227/orgsyn.064.0127| title = HYDROXYLATION ...=Transition-metal peroxide reactions. Synthesis of &alpha;-hydroxycarbonyl compounds from enolates|journal=The Journal of Organic Chemistry|volume=43|issue=2|pa ...
    7 KB (958 words) - 15:31, 8 February 2025
  • {{short description|Class of chemical compounds}} ...orosilanes provides a well-tested route. Bulky substituents such as [[tris(trimethylsilyl)silane|(Me<sub>3</sub>Si)<sub>3</sub>Si]] stabilize the iminoborane with re ...
    11 KB (1,471 words) - 06:53, 16 January 2025
  • ...st2= Wilen |first3= L.N. |last3= Mander |title= Stereochemistry of Organic Compounds |publisher= Wiley |location= New York |year= 1994 |isbn= 81-224-0570-3}}</r ...elative apparent sizes determine the differences in steric effects between compounds. Thus, A-values are useful tools in determining compound reactivity in chem ...
    13 KB (1,810 words) - 11:33, 23 January 2025
  • ...place. The chlorine atoms liberated from the chlorosilane are tied to the trimethylsilyl groups of HMDS so that no chlorine-containing solid salts are formed.<ref>" ...le examples of silazanes are disilazane {{chem2|H3Si\sNH\sSiH3}} and [[bis(trimethylsilyl)amine|hexamethyldisilazane]] {{chem2|(H3C)3Si\sNH\sSi(CH3)3}}. If only one ...
    19 KB (2,638 words) - 02:31, 2 December 2024
  • ...=81|year=1987|doi=10.15227/orgsyn.065.0081|title=Methylenation of Carbonyl Compounds: (+)-3-Methylene-''cis-p''-menthane}}</ref><ref>{{cite journal | last1 = Ma ...R<sub>2</sub>) base (e.g., [[Lithium diisopropylamide|LDA]], [[Lithium bis(trimethylsilyl)amide|LHMDS]]). Subsequently, the enolate is reacted with [[Eschenmoser's ...
    8 KB (1,071 words) - 08:05, 13 April 2024
  • ...Their strain also make them of interest in the development of energy-dense compounds. ...oducts. Tetramethylammonium fluoride is then added to remove the remaining trimethylsilyl group and the chloride, generating the <sup>''t''</sup>Bu<sub>3</sub>C<sub> ...
    42 KB (5,833 words) - 17:00, 19 January 2025
  • ...s controlled through exposure to light. Because Photoresists are non polar compounds, and silicon dioxide has a polar character, adhesion problems can manifest * [[Bis(trimethylsilyl)amine|HMDS]] ...
    14 KB (2,044 words) - 08:27, 24 July 2023
  • ...fluoroform]] (HFC-23) in the presence of P<sub>4</sub>-''t''-Bu and [[tris(trimethylsilyl)amine]].<ref>{{citation |author=S. Okusu |author2=K. Hirano |author3=E. Tok : [[Category:Phosphorus compounds]] ...
    15 KB (2,076 words) - 06:15, 6 February 2025
  • ...combination of partially-condensed tetrasilanolphenyl POSS with [[Terbium compounds|terbium acetate]] and/or [[Europium(III) acetate|europium acetate]] (at dif {{silicon compounds}} ...
    34 KB (4,467 words) - 01:43, 9 November 2024