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  • {{correct title|reason=bracket|Tetrakis[3,5-bis(trifluoromethyl)phenyl]borate}} ...= R. G.|title = Safe Preparation and Purification of Sodium Tetrakis[(3,5-trifluoromethyl)phenyl]borate (NaBArF<sub>24</sub>): Reliable and Sensitive Analysis of Wat ...
    11 KB (1,478 words) - 06:49, 25 June 2024
  • ...aminosulfuranes''' is a chemical reaction that transforms oxidized organic compounds into [[organofluorine compound]]s. Aminosulfuranes selectively exchange hyd ...sulfur tetrafluoride, aminosulfuranes do not convert carboxylic acids into trifluoromethyl groups; the reaction halts at the acyl fluoride stage.<ref>Markovskii, N.; ...
    11 KB (1,487 words) - 22:33, 21 December 2023
  • ...nd thus can be used for alpha-[[hydroxylation]] of [[carbonyl]]-containing compounds.<ref>{{Cite journal | doi = 10.15227/orgsyn.064.0127| title = HYDROXYLATION ...=Transition-metal peroxide reactions. Synthesis of &alpha;-hydroxycarbonyl compounds from enolates|journal=The Journal of Organic Chemistry|volume=43|issue=2|pa ...
    7 KB (958 words) - 15:31, 8 February 2025
  • ...Crowded and Electron-withdrawing Group: Synthesis and Acidity of Pentakis(trifluoromethyl)benzene, -toluene, -phenol, and -aniline ...tautomerism]]. This effect is especially pronounced in [[1,3-dicarbonyl]] compounds that can form [[hydrogen-bonding|hydrogen-bonded]] enols. The [[equilibrium ...
    17 KB (2,405 words) - 20:14, 18 October 2024
  • ...ite web |title=Electrochemical Series of Photocatalysts and Common Organic Compounds |url=https://yoon.chem.wisc.edu/sites/yoon.chem.wisc.edu/files/Merck-Photoc ...mplex molecules. However, the condensation of [[amines]] with [[carbonyl]] compounds to form iminium ions is often unfavorable, sometimes requiring harsh dehydr ...
    50 KB (6,878 words) - 14:17, 29 November 2024
  • ...ember of the [[group 10 element|group 10]] of the [[periodic table]]. Most compounds in the group have an [[oxidation state]] of +2. Nickel is classified as a [ ...s, as nickel is adjacent to copper and iron in the periodic table can form compounds with the same structure as the [[high-temperature superconductor]]s that ar ...
    56 KB (8,268 words) - 21:58, 16 February 2025
  • ...combination of partially-condensed tetrasilanolphenyl POSS with [[Terbium compounds|terbium acetate]] and/or [[Europium(III) acetate|europium acetate]] (at dif ...lectrophilic]] centers that are approximately as electron-withdrawing as a trifluoromethyl group, leading to increased catalytic activity.<ref name=Feher1994>{{cite j ...
    34 KB (4,467 words) - 01:43, 9 November 2024
  • ...also play a key role in the intermediary metabolism of various biological compounds. Such radicals can even be messengers in a process dubbed [[redox signaling ...one-electron [[redox|reduction]]s. Typically one-electron reduced organic compounds are unstable. Stability is conferred to the radical anion when the charge c ...
    41 KB (5,661 words) - 05:28, 1 March 2025