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...und in many [[salt (chemistry)|salt]]s, many [[organic chemistry|organic]] compounds containing [[ester]]s of it have been made, and the parent [[carbonic acid] ...mamoto |first3= D. Stanley |last3= Tarbell |year= 1977 |title= Di-''tert''-Butyl Dicarbonate |volume= 57 |pages= 45 |collyear= 1988 |collvol= 6 |collvolpage ...

| PIN=''N''²-''tert''-Butyl-6-chloro-''N''⁴-ethyl-1,3,5-triazine-2,4-diamine ...1958 inv., [[Geigy]] lab) and [[simazine]], it has a [[tert-butyl|''tert''-butyl]] group {{chem2|\s[C\s(CH3)3]}} in place of the [[isopropyl]] {{chem2|\s[CH ...

...butyl substituent; therefore the most stable conformation has the ''tert''-butyl in the equatorial position.]] ...n A-value of ~5. Because the A-value of ''tert''-butyl is higher, ''tert''-butyl has a larger [[steric effect]] than methyl. This difference in steric effec ...

{{short description|Class of chemical compounds}} ...:TBuN=B-tBu (CETSUP).png|thumb|right|Structure of tBuN=B-tBu (tBu = [[tert-butyl]]). The B-N bond distance is 126 pm.<ref name=PPaetz/>]] ...

...groups as R¹, a [[methyl group]] or [[tert-butyl group|''tert''-butyl group]] as and even-numbered ''x'' between 0 and 6 (P₄-''t''-Bu: ...}}] with phosphorus pentachloride and ''tert''-butylammonium chloride to ''tert''-butylphosphorimide trichloride (5)<ref>{{citation |author=R. Schwesinger ...

...unwald56>{{cite journal| title = Correlation of Solvolysis Rate III. ''t''-Butyl Chloride In a Wide Range of Solvent Mixtures | journal= [[J. Am. Chem. Soc. The [[substitution reaction]] of [[tert-Butyl chloride]] was chosen as reference reaction. The first step, ionizing step, ...

...Their strain also make them of interest in the development of energy-dense compounds. ...species, like [[cubane]] and [[dodecahedrane]]. The [[Tert-butyl|''tert''-butyl]] substituents were used to encumber the tetrahedral core and quell the [[R ...

...tautomerism]]. This effect is especially pronounced in [[1,3-dicarbonyl]] compounds that can form [[hydrogen-bonding|hydrogen-bonded]] enols. The [[equilibrium ...able shows the relative solvolysis rates of [[tert-Butyl chloride|''tert''-butyl chloride]] with [[acetic acid]] (CH₃CO₂H), [[methanol ...

...–PMe 2 )(η 2 -CH–PMe 2 ) and synthesis of related molybdenum and tungsten compounds |url=http://xlink.rsc.org/?DOI=C39830001101 |journal=J. Chem. Soc., Chem. C ...''-W(PMe₃)₄Se₂ can also react with [[Tert-Butyl isocyanide|''^t''BuNC]] (''^t''Bu=C(CH₃)<sub ...

...les: [[aldehyde]]s and [[ketone]]s, [[Carboxylic Acid Derivatives#Carbonyl compounds|carboxylic acid-derivatives]], and the carbon-carbon double bonds of [[alke ...lision) of a [[nucleophile]] on a [[trigonal]] [[Saturated and unsaturated compounds|unsaturated]] center of an [[electrophile|electrophilic]] [[molecule]] (the ...

...ydrogen bonding terms. This allows the prediction of polar and associative compounds, which most [[solubility]] parameter models have been found to do poorly. I ...g activity coefficients of binary systems of non-polar, polar and hydrogen compounds, but no water. As can be seen in the deviation chart, the systems with wate ...

...on Diradical Characters and Nonlinear Optical Properties of 1,3-Diradical Compounds |url=https://pubs.acs.org/doi/10.1021/jp508657s |journal=The Journal of Phy ...itio and Density Functional Investigation of [Ni(LISQ)2] (LISQ=3,5-di-tert-butyl-o-diiminobenzosemiquinonate(1-)) |url=https://pubs.acs.org/doi/10.1021/ja03 ...

...ition (CI) engines and [[Ethanol fuel|bioethanol]] or [[ETBE]] (ethyl tert-butyl ether) produced from bioethanol in spark ignition (SI) engines. As early as ...

...00121a010|pmid=1737021|citeseerx=10.1.1.539.2952}}</ref> or identify small compounds,<ref>{{Cite journal|last1=Caligiani|first1=A.|last2=Acquotti|first2=D.|last ...=10.1016/0016-7037(80)90155-6|bibcode=1980GeCoA..44..649S}}</ref> as these compounds are easily separated. Another advantage of methane for compound-specific me ...