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{{Short description|Series of chemical reactions by which compounds exchange ligands}} ...{{ISBN|0-471-05545-X}}</ref><ref>R. G. Wilkins "Kinetics and Mechanism of Reactions of Transition Metal Complexes," 2nd Edition, VCH, Weinheim, 1991. {{ISBN|1- ...

...9.conrr179 |chapter=Darzens Halogenation |title=Comprehensive Organic Name Reactions and Reagents |date=2010 |pages=846–847 |isbn=9780471704508 }}</ref> {{Organic reactions}} ...

....<ref>{{JerryMarch}}</ref> The reaction is called [[nucleophilic aliphatic substitution]] (of the halide), and the reaction product is a higher substituted amine. ...cleophilic to undergo direct alkylation, often under mild conditions. The reactions are complicated by the tendency of the product (a primary amine or a second ...

[[Image:TBuCl.jpg|frame|right|S_N1 mechanism of substitution reaction]] ...= The Correlation of Solvolysis Rates and the Classification of Solvolysis Reactions into Mechanistic Categories | journal= [[J. Am. Chem. Soc.]]|year = 1951 | ...

...Due to the environmental and safety impact of non-recyclable, high energy reactions with <chem>HCl</chem>, an alternative synthesis of a shelf-stable germanium ...is of much note since the sole byproduct of this reaction is water. These reactions could provide an alternative to normal oxide separations for other metals t ...

...ns) or coupled Michaelis–Menten and Monod reaction orders (for biochemical reactions). However, conversely to Michaelis–Menten kinetics, GEBIK and GEBIF equatio ...be satisfied. For example, the <chem>N2</chem> product in which 1 isotopic substitution occurs (e.g., <chem>^{15}N^{14}N</chem>) will be described by <chem>^1_2P</ ...

...[[mechanochemical]] techniques where physical methods are used to control reactions in the absence of solvent. ...ound-state orientation). Thus, equilibrium-solvent effects are observed in reactions that tend to have sharp barriers and weakly dipolar, rapidly relaxing solve ...

...-3.00533-4|year=2014|pages=1582–1620|volume=5|chapter=5.32 Hydrovinylation Reactions in Organic Synthesis|isbn=978-0-08-097743-0}}</ref> ...sic Beta-Si Elimination by Ni-NHC Cooperation: Implication for C–C Forming Reactions Involving Ni-Alkyl-Beta-Silanes | issue = 10 | pmid = 22116100 | journal = ...

{{Short description|Mathematical model for modelling chemical reactions}} ...bond activation]], [[1,3-Dipolar cycloaddition|1,3-dipolar cycloaddition]] reactions, among others.<ref name="Wolters-2015" /><ref name="Fernández-2014" /><ref ...

...red to stabilize Rh(V). This oxidation state is invoked in [[borylation]] reactions. ...aliphatic C-H borylation-1.jpg|center|450px|thumb|Rh-catalyzed borylation reactions involve Rh(V) intermediates.]] ...

|Type = Substitution reaction ...or1-last=Knipe|editor1-first=A.C.|title=March's Advanced Organic Chemistry Reactions, Mechanisms, and Structure.|date=2007|publisher=John Wiley & Sons|location= ...

Substitution into the equation above for the control volume ''cv'' yields: ...

The substitution of carbons in the tetrahedral core of tetrahedrane with pnictogens to stabi ...rst3=Christopher C. |date=2021-08-25 |title=Dimerization and Cycloaddition Reactions of Transient Tri- tert -butylphosphacyclobutadiene Generated by Lewis Acid ...

...ex reaction kinetics are involved, for example chemical substitution, side reactions or degradation, one may still apply the theory by computing <math> u(n,t) < [[Category:Polymerization reactions]] ...

...sition-Metal Ions in Aqueous Aolution: an EXAFS Study of Electron-Exchange Reactions|journal=J. Am. Chem. Soc.|year=1980|volume=102|issue=18|pages=5904–5906|doi ==Reactions== ...

[[File:Toluene Halogenation Reactions V.2.svg|thumb|Reaction scheme of the photochlorination of the [[methyl grou ...nsitivity of this reaction.<ref>Jean-Baptiste Dumas: ''Über das Gesetz der Substitution und die Theorie der Typen'', Lieb. Ann., Vol. 33, 1840, p.&nbsp;259–300.</r ...

...rmation (axial substitution) and the lower energy conformation (equatorial substitution) is the A-value for that particular substituent. ...rence in steric effects can be used to help predict reactivity in chemical reactions. ...

...]] (CODH) are integral enzymes in this one pathway and can perform diverse reactions in the [[carbon cycle]] as a result. Because of this, the exact activity of ...| pmid = 15491124 | doi = 10.1021/ar040002e }}</ref> The two main overall reactions are as follows: ...

...Ph)(CF3)2)4: A Hydrocarbon-Soluble Catalyst for Carbon−Carbon Bond-Forming Reactions|url=https://doi.org/10.1021/om9604031|journal=Organometallics|volume=15|iss ...lts can also be prepared via the same synthetic route, from the metathesis reactions of Li⁺[Al(O''pftb'')₄]⁻ with the correspon ...

...s such as they are not without [[chain transfer]] or [[chain termination]] reactions.<ref name=Szwarz1956>{{Cite journal ...merization cannot be a truly living process due to unavoidable termination reactions between two radicals. The commonly-used term controlled radical polymerizat ...