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...eactivity. Closed-shell reactivity (e.g., [[Pericyclic reaction|pericyclic reactions]]) is best understood using the delocalized molecular orbital picture, whil ...aloid [P(μ-NTer)₂]₂ can undergo concerted pericyclic reactions with single bonds (H₂), double bonds (alkenes, aldehydes), and t ...

...the excited electron. This pathway is slow because it is [[Spin-forbidden reactions|spin-forbidden]] so the triplet excited state has a substantial average lif ...thus is an additional parameter to consider when developing new photoredox reactions. ...