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[[Image:TBuCl.jpg|frame|right|S_N1 mechanism of substitution reaction]] ...= The Correlation of Solvolysis Rates and the Classification of Solvolysis Reactions into Mechanistic Categories | journal= [[J. Am. Chem. Soc.]]|year = 1951 | ...

....<ref>{{JerryMarch}}</ref> The reaction is called [[nucleophilic aliphatic substitution]] (of the halide), and the reaction product is a higher substituted amine. ...cleophilic to undergo direct alkylation, often under mild conditions. The reactions are complicated by the tendency of the product (a primary amine or a second ...

...[[mechanochemical]] techniques where physical methods are used to control reactions in the absence of solvent. ...ound-state orientation). Thus, equilibrium-solvent effects are observed in reactions that tend to have sharp barriers and weakly dipolar, rapidly relaxing solve ...

...Due to the environmental and safety impact of non-recyclable, high energy reactions with <chem>HCl</chem>, an alternative synthesis of a shelf-stable germanium ...is of much note since the sole byproduct of this reaction is water. These reactions could provide an alternative to normal oxide separations for other metals t ...

..., generating an [[epoxide]]. This epoxide is then opened by regioselective nucleophilic attack of halide anion at C7. The resultant halohydrin is dehydrated to for ...y, in chemical synthesis, arenes are halogenated by electrophilic aromatic substitution, a process that often suffers from poor regioselectivity and makes use of t ...

...nes. XXVI. The identification of the formyl donors of the transformylation reactions | journal = The Journal of Biological Chemistry | volume = 234 | issue = 7 This tetrahydrofolate (THF)–dependent enzyme catalyzes a nucleophilic acyl substitution of the formyl group from 10-formyltetrahydrofolate (fTHF) to N¹- ...

...uthor2=Jordan, A. M.|title=The medicinal chemist's toolbox: an analysis of reactions used in the pursuit of drug candidates|journal=J. Med. Chem.|year=2011|volu ...gement]] and the [[Diels-Alder|Diels-Alder cycloaddition]] are examples of reactions that are 100 percent atom economical. On the other hand, a prototypical [[W ...