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  • * [[Reductive elimination]]: {{Organic reactions}} ...
    2 KB (329 words) - 22:21, 26 August 2023
  • ...nic molecules that can exhibit more complex, multi-step disproportionation reactions. ...taken, or abstracted by the acceptor as the donor molecule undergoes an [[elimination reaction]] to form a [[double bond]].<ref name = "Cross">Kelley, Richard D. ...
    9 KB (1,233 words) - 22:56, 8 February 2024
  • ===Methylene-for-oxo reactions=== ...], respectively to give the α-methylene carbonyl compound. If the Hofmann elimination is used, the process can be represented as follows: ...
    8 KB (1,071 words) - 08:05, 13 April 2024
  • ...-3.00533-4|year=2014|pages=1582–1620|volume=5|chapter=5.32 Hydrovinylation Reactions in Organic Synthesis|isbn=978-0-08-097743-0}}</ref> ...sic Beta-Si Elimination by Ni-NHC Cooperation: Implication for C–C Forming Reactions Involving Ni-Alkyl-Beta-Silanes | issue = 10 | pmid = 22116100 | journal = ...
    7 KB (895 words) - 18:36, 18 November 2024
  • ...es that cannot be identified directly but which are inferred from trapping reactions.<ref name="Johnson">{{cite journal |author1=Johnson, C.C. |author2=Lippard, Radical clock reactions involve a competition between a [[unimolecular]] [[Radical (chemistry)|radi ...
    8 KB (1,212 words) - 17:56, 9 November 2023
  • ...Akira |author2-link=Akira Suzuki |title=Palladium-Catalyzed Cross-Coupling Reactions of Organoboron Compounds. |journal=[[Chemical Reviews]] |year=1995 |volume= ...e, forming a coupling product and regenerating Pd<sup>0</sup> ([[reductive elimination]]).<ref name="1995 Suzuki review"/> ...
    6 KB (788 words) - 12:03, 7 February 2025
  • {{Short description|Mathematical model for modelling chemical reactions}} ...bond activation]], [[1,3-Dipolar cycloaddition|1,3-dipolar cycloaddition]] reactions, among others.<ref name="Wolters-2015" /><ref name="Fernández-2014" /><ref ...
    13 KB (1,939 words) - 06:17, 22 April 2024
  • ...eactions|year=2009|doi=10.1002/0471264180.or072.02|chapter=Desulfonylation Reactions|isbn=978-0471264187}}</ref> ...y. α-Sulfonyl [[carbanion]]s may be used as [[nucleophile]]s in alkylation reactions, Michael-type additions, and other processes.<ref>{{cite journal|doi=10.107 ...
    20 KB (2,705 words) - 05:09, 29 November 2024
  • ...al of the small molecule from the metal-ligand bond is called extrusion or elimination. ...on=Examples of type 1,1 (a) and 1,2 (b) resulting geometries for insertion reactions ...
    17 KB (2,325 words) - 16:30, 17 May 2024
  • ...[[mechanochemical]] techniques where physical methods are used to control reactions in the absence of solvent. ...ound-state orientation). Thus, equilibrium-solvent effects are observed in reactions that tend to have sharp barriers and weakly dipolar, rapidly relaxing solve ...
    17 KB (2,405 words) - 20:14, 18 October 2024
  • ...olander|first1=Gary A. |last2=Harris |first2=Christina R.|title=Sequencing Reactions with Samarium(II) Iodide |journal=Chemical Reviews|volume=96|pages=307–338 ...u of HMPA as an activator for SmI<sub>2</sub> reductions, producing faster reactions and similar yields while avoiding the use of a known carcinogen.<ref>{{cite ...
    17 KB (2,375 words) - 21:27, 29 August 2024
  • Radical formation reactions due to the decomposition of water by ultrasound can be described this way: ...mistry and sonocatalysis: Harnessing sound for enhanced catalytic-assisted reactions ». Consulté le 26 février 2024. https://new.societechimiquedefrance.fr/wp-c ...
    16 KB (2,109 words) - 17:19, 10 December 2024
  • ...red to stabilize Rh(V). This oxidation state is invoked in [[borylation]] reactions. ...aliphatic C-H borylation-1.jpg|center|450px|thumb|Rh-catalyzed borylation reactions involve Rh(V) intermediates.]] ...
    10 KB (1,353 words) - 12:18, 20 February 2025
  • ...be derived from the unfavorable [[Beta-Hydride elimination|&beta;-hydride elimination]]. Computational calculations have determined that [[London dispersion forc ...st=Kathryn Lynn |url=http://worldcat.org/oclc/83966357 |title=Photoinduced reactions of group VI organotransition metal complexes |oclc=83966357}}</ref> ...
    16 KB (2,218 words) - 02:25, 22 March 2024
  • ...trafluoride]]. Attack of the hydroxyl group of the substrate on sulfur and elimination of hydrogen fluoride lead to an alkoxyaminosulfur difluoride intermediate. ...mmonium fluorides can be used to displace sulfonate esters; however, these reactions require higher temperatures than aminosulfurane fluorination of the corresp ...
    11 KB (1,487 words) - 22:33, 21 December 2023
  • == Reactions == ...als, stibanes [[Vicinal (chemistry)|vicinal]] to a [[leaving group]] can [[Elimination reaction|eliminate]] before a proton. For example, diphenyl(β-hydroxyphene ...
    8 KB (1,163 words) - 22:25, 7 February 2025
  • Elimination of fluoro- or chlorosilanes provides a well-tested route. Bulky substituent ===Addition reactions=== ...
    11 KB (1,471 words) - 06:53, 16 January 2025
  • ...rbonisation of limestone and dehydration of clay or gypsum), and reduction reactions. The agglomerate then becomes, at equal weight, richer in iron than the ore Another advantage is the elimination of undesirable elements: the chain agglomeration process eliminates 80-95% ...
    12 KB (1,791 words) - 05:39, 3 September 2024
  • ...are known to produce radicals. Radicals are intermediates in many chemical reactions, more so than is apparent from the balanced equations. ...ed from other radicals through substitution, [[addition]], and elimination reactions. ...
    41 KB (5,661 words) - 05:28, 1 March 2025
  • ...advection|advective]]-[[dispersive mass transfer]], as well as geochemical reactions, such as [[adsorption]] onto soils and [[Solvation|dissolution]] / [[precip Molecules behaviour in relation to aqueous dissociation reactions is typically related to their [[acid dissociation constant]]s, that are typ ...
    35 KB (4,732 words) - 16:57, 30 January 2024
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