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  • ...= H. | year = 1983 | title = Selective grignard-type carbonyl addition of alkenyl halides mediated by chromium(II) chloride| journal = Tetrahedron Letters| ...year = 1986 | title = Reactions of alkenylchromium reagents prepared from alkenyl trifluoromethanesulfonates (triflates) with chromium(II) chloride under nic ...
    13 KB (1,579 words) - 16:13, 25 December 2024
  • ...PPh<sub>3</sub>)<sub>4</sub>]]/NaHC(CO<sub>2</sub>Et)<sub>2</sub>). Alkyl, alkenyl, and allylic sulfones may be reduced using one or more of these methods. ...able radical. Thus, S-alkyl bonds are cleaved in preference to S-aryl or S-alkenyl bonds.<ref>{{cite journal | last1 = Horner | first1 = L. | last2 = Neumann ...
    20 KB (2,705 words) - 05:09, 29 November 2024
  • ...[[Henri Kagan]] observed the reduction of a variety of organic functional groups by samarium(II) iodide under mild conditions.<ref name=orig>{{cite journal ...protic solvent) steps.<ref name=Mol/><ref name=eros/> Reducible functional groups include: ...
    17 KB (2,375 words) - 21:27, 29 August 2024
  • ...formula]] [RSiO<sub>3/2</sub>]<sub>n</sub> (R = H, [[alkyl]], [[aryl]], [[alkenyl]] or [[alkoxyl]].).<ref name=Guizhi2001>{{cite journal ...>8</sub>O<sub>12</sub>. In all cases each Si center is bonded to three oxo groups, which in turn connect to other Si centers. The fourth group on Si is usua ...
    34 KB (4,467 words) - 01:43, 9 November 2024
  • ...n M. R. |last4= Stephenson, Corey R. J. |title=Engaging unactivated alkyl, alkenyl and aryl iodides in visible-light-mediated free radical reactions|journal=N ...This reaction was demonstrated to be orthogonal to many common protecting groups when a base was added to neutralise the HBr produced. ...
    50 KB (6,878 words) - 14:17, 29 November 2024