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- Ammoxidation of alkenes exploits the weak C-H bonds that are located in the [[allyl]]ic position of Instead of alkenes, [[Alcohol (chemistry)|alcohol]]s and [[aldehyde]]s are competent substrate ...4 KB (564 words) - 15:23, 8 June 2024
- === Terminal alkenes === ...lar weight internal [[alkenes]] can be converted to more valuable terminal alkenes. The [[Shell higher olefin process]] (SHOP process) uses ethenolysis on an ...6 KB (816 words) - 16:17, 28 November 2024
- ...in organic synthesis, especially in the Simmons–Smith cyclopropanation of alkenes. In this process, the couple (typically a slurry in an [[diethyl ether|eth ...ng of [[carbonyl compounds]], and to [[redox|reduce]] electron-deficient [[alkenes]] and [[alkynes]]. [[Sonication]] has been employed to enhance the rate of ...5 KB (727 words) - 22:49, 31 March 2024
- ...a hydrovinylation. In the '''Dimersol''' and '''Alphabutol''' Processes, alkenes are dimerized for the production of gasoline and for comonomers such as 1-b ...le was provided by the [[Murai reaction]], which involves the insertion of alkenes into a C-H bond of [[acetophenone]]. The keto group directs the regiochemi ...7 KB (895 words) - 18:36, 18 November 2024
- ...e [[1,3-dipolar cycloaddition]] to dipolarophiles: with electron-deficient alkenes, good yields of [[pyrroline]]s are obtained. [[Alkyne]]s, carbonyl compound ...3 KB (449 words) - 10:49, 28 August 2024
- ...|issue=2 |pages=264–265 |doi=10.1021/jo01084a635 |issn=0022-3263}}</ref> Alkenes undergo both C=C methylenation and C–H methylenation insertion to give a mi ...8 KB (1,071 words) - 08:05, 13 April 2024
- ...ed to convert β-sulfonyloxy or β-[[acyloxy]] sulfones to the corresponding alkenes. The key mechanistic step of this process is elimination of an anionic or [ ...ation of essentially free alkyl anions,<ref name=ballah/> leads to (''E'') alkenes with extremely high selectivity. Samarium(II) iodide also produces the (''E ...20 KB (2,705 words) - 05:09, 29 November 2024
- ...occurs only if the overall reaction is thermally favorable. In the case of alkenes, this is due to [[isomerization]] of the monomer double bond; for heterocyc ===Alkenes=== ...22 KB (3,258 words) - 12:12, 10 December 2024
- ...[norbornene]] are highly reactive compared to conjugated and electron-poor alkenes ([[butadiene]] and [[methoxyethene]]). In the case of [[norbornene]] and vi ...ain-transfer is the rate-limiting step, while in the case of less reactive alkenes, such as vinyl silazanes, propagation is the rate-limiting step. The thiol' ...25 KB (3,313 words) - 12:04, 4 January 2025
- ...f the alkyl halide, reductive fragmentation to a diastereomeric mixture of alkenes may occur. β-Elimination of the intermediate organosamarium species leads t ...ompatible with a variety of functional groups, including alcohols, arenes, alkenes, and esters. Aryl halides are reduced to the corresponding halogen-free aro ...17 KB (2,375 words) - 21:27, 29 August 2024
- *[[Carbostannylation of Alkynes and Alkenes]] *[[Carbocyanation of Alkynes and Alkenes]] ...13 KB (1,579 words) - 16:13, 25 December 2024
- The insertion of carbon monoxide and alkenes into metal-carbon bonds is a widely exploited reaction with major industria ...emistry of the reactions. The reverse reaction, the de-insertion of CO and alkenes, are of fundamental significance in many catalytic cycles as well. ...17 KB (2,325 words) - 16:30, 17 May 2024
- ...|last3=Akita, Munetaka |title=Intermolecular Aminotrifluoromethylation of Alkenes by Visible-Light-Driven Photoredox Catalysis|journal=Organic Letters|date=3 ...=Catalytic hydrotrifluoromethylation of styrenes and unactivated aliphatic alkenes via an organic photoredox system|journal=Chemical Science|year=2013|volume= ...50 KB (6,878 words) - 14:17, 29 November 2024
- ...ctivity.gif|thumb|upright=1.7|'''Reactions of manganese-oxo complexes with alkenes.''' Depending on the spin state of the starting material, triplet or quinte ...12 KB (1,706 words) - 20:41, 7 August 2024
- ==== Alkenes ==== ...37 KB (4,675 words) - 02:31, 11 November 2024
- However, the reaction proceeds slowly with unstrained alkenes.<ref>{{cite video|first1=George|last1=Gilbert|first2=Jerrold J.|last2= ...12 KB (1,648 words) - 01:44, 12 February 2025
- ...Adam's investigations into the ene-reaction of singlet oxygen with acyclic alkenes.<ref name=rumbach-1994 /> Through the cis effect and the presence of approp ...14 KB (2,059 words) - 03:44, 29 November 2024
- ...educed selectively in the presence of 1,2-disubstituted or monosubstituted alkenes.<ref>{{cite journal |last1=Kursanov |first1=D. N. |last2=Parnes |first2=Z. ...13 KB (1,710 words) - 17:57, 15 August 2024
- 36 KB (5,159 words) - 09:29, 26 February 2025
- ..., which is attributed to the formation of [[polyene]]s from these terminal alkenes.<ref name=Geuskens1978 /> ...me="Decker-PVC" /> Radicals formed at hydrocarbon sites rapidly convert to alkenes with loss of radical chlorine. This forms [[allylic]] hydrogens (shown in r ...43 KB (5,920 words) - 08:04, 13 January 2025