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...[[monomer]]s. When a polymer is at its ceiling temperature, the rate of [[polymerization]] and [[depolymerization]] of the polymer are equal. Generally, the ceilin ==Thermodynamics of polymerization== ...

...nic molecules that can exhibit more complex, multi-step disproportionation reactions. ...9. {{doi|10.1021/j100266a042}}</ref> In the most common disproportionation reactions, a hydrogen atom is taken, or abstracted by the acceptor as the donor molec ...

...on is possible through analyzing the limiting reagent of the [[step-growth polymerization]].<ref name ="Flory, P.J."/> # All reactions occur between A and B ...

{{short description|Type of chain polymerization}} ...EP-08-04-03|doi-access=free}}</ref><br/>See also [[reversible-deactivation polymerization]] RDP. ...

{{short description|Polymerization reaction initiated by a charge transfer to a monomer}} ...<ref name='Gold Book "cationic polymerization"'>{{cite web |title=cationic polymerization |url=https://goldbook.iupac.org/terms/view/C00910 |website=Gold Book |publi ...

...esides|first7=George M.|last8=Sikes|first8=Hadley D.|date=2015-01-22|title=Polymerization-based signal amplification for paper-based immunoassays|journal=Lab Chip|la ...es|first2=H. D.|date=2016-02-01|title=Using photo-initiated polymerization reactions to detect molecular recognition|journal=Chem. Soc. Rev.|language=en|volume= ...

...erization. One phase is above the interface, and the other phase is below. Polymerization occurs where the two phases meet, at the interface.]] ...n of thin-film composite hollow fiber and tubular membranes by interfacial polymerization|journal=Journal of Membrane Science|volume=192|issue=1–2|pages=41–54|doi=10 ...

...te=21 May 2013}}</ref> Such a structure was synthesized via the controlled polymerization of multivinyl monomers, which was first reported in Dr. Wenxin Wang's resea ...1/ma0707133|bibcode=2007MaMol..40.7184W}}</ref> to kinetically control the polymerization by increasing the ratio of inactive copper(II) [[catalyst]] to active coppe ...

...in viscosity.<ref>{{cite book |doi=10.1002/047147875x |title=Principles of Polymerization |year=2004 |last1=Odian |first1=George |isbn=0471274003 }}</ref> This "infi According to the [[Carothers equation]] number-average degree of polymerization <math>DP_n</math> is given by ...

...ex reaction kinetics are involved, for example chemical substitution, side reactions or degradation, one may still apply the theory by computing <math> u(n,t) < ...itle = Dynamic Networks that Drive the Process of Irreversible Step-Growth Polymerization | journal = Scientific Reports | volume = 9 | issue = 1 | pages = 2276 | da ...

...how considerable [[Lewis acidity]] and can initiate epoxide polymerization reactions.<ref name="Beckett">M.A. Beckett, G.C. Strickland, J.R. Holland, and K.S. V ...

== Reactions == ...CID|2047780}}.</ref><ref name="goto">Katsumi Goto (1956): "Effect of pH on Polymerization of Silicic Acid". ''Journal of Physical Chemistry'', volume 60, issue 7, pa ...

...group]]s (α-olefins), which are more amenable to other reactions such as [[polymerization]] and [[hydroformylation]]. ...first3 = Peter | last4 = Hoveyda | first4 = Amir H. | title = Ethenolysis Reactions Catalyzed by Imido Alkylidene Monoaryloxide Monopyrrolide (MAP) Complexes o ...

...yclopropenimine superbases. Direct neutral Bronsted base catalyzed Michael reactions with α-aryl esters|volume=137|issue=32|pages=10246–10253|date=2015|doi=10.1 ...very strong solubilization effect also an extreme acceleration of addition reactions even at temperatures below -78&nbsp;°C. ...

...nd sequence and are analysed via statistical measures (e. g. the degree of polymerization, comonomer composition or dyad and triad fractions).<ref name=":0">{{Cite j ...e and is used, for example, to observe the progress of transesterification reactions between [[polyethylene terephthalate]] (PET) and [[polyethylene naphthalate ...

...transition metal-carbon bonds|editor=Hartley and Patai}}</ref> When these reactions are reversible, the removal of the small molecule from the metal-ligand bon ...on=Examples of type 1,1 (a) and 1,2 (b) resulting geometries for insertion reactions ...

...duct is [[chiral]], hence there is interest in asymmetric variants. These reactions invariably involve metal-[[acetylide]] intermediates. ...hael B.|last2=March|first2=Jerry|title=March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure|url=https://archive.org/details/marchsadvancedor ...

...ref> This reaction is accepted as a [[click chemistry]] reaction given the reactions' high [[Yield (chemistry)|yield]], [[stereoselectivity]], high [[Reaction r ...zation depending on the thiol and ene functional groups. This free-radical polymerization can be useful in the synthesis of uniform polymer networks.<ref name=Northr ...

...ity of the complexes, it was demonstrated to participate in organometallic reactions. Subsequently, [[William J. Evans (chemist)|William J. Evans]] and his cowo ...reactivity.<ref name=":10" /> These special properties allow the following reactions to occur. ...

...are known to produce radicals. Radicals are intermediates in many chemical reactions, more so than is apparent from the balanced equations. Radicals are important in [[combustion]], [[atmospheric chemistry]], [[polymerization]], [[Plasma (physics)|plasma]] chemistry, [[biochemistry]], and many other ...