Lomonosovite
Template:Short description Template:Infobox mineral
Lomonosovite is a phosphate–silicate mineral with the idealized formula Na10Ti4(Si2O7)2(PO4)2O4 [1] early Na5Ti2(Si2O7)(PO4)O2 or Na2Ti2Si2O9*Na3PO4.[2]
The main admixtures are niobium (up to 11.8% Nb2O5), manganese (up to 4.5 %MnO) and iron (up to 2.8%).[3]
Discovery and name
The mineral was discovered by V.I. Gerasimovskii [4] in Lovozersky agpaitic massif. Named for Mikhail Lomonosov – famous Russian poet, chemist and philosopher, but the earlier – mining engineer.[5]
Crystal structure
According to X-ray data, lomonosovite structure was determined is triclinic unit cell with parameters: a = 5.44 Å, b = 7.163 Å, c = 14.83 Å, α = 99°, β = 106°, and γ = 90°, usually centrosymmetric (sp. gr. P-1),[6] but acentric varieties (polytype) are also reported.[3]
The crystal structure of lomonosovite is based on three-layer HOH packets consisting of a central octahedral O layer and two outer heteropolyhedral H layers. Ti- and Na centered octahedra are distinguished in the O layer, whereas the H layers are composed of Ti-centered octahedra and Si2O7 diorthogroups, (like in other heterophyllosilicates, for example lamprophyllite). The interpacket space includes Na+ cations and PO43- anions.[6]
Properties
Lomonosovite forms lamellar and tabular crystals with perfect cleavage. It is macroscopically brown, from cinnamon-brown to black. It is transparent in thin plates. The luster vitreous to adamantine.
Its pleochroism is strong from colorless to brown. The refractive index is = 1.654–1.670 = 1.736 – 1.750 =1.764–1.778 2V=56–69.[2]
Hardness 3–4 Density 3.12 – 3.15.[2]
Origin
Accessory mineral of peralkaline agpaitic nepheline syenites (like Khibina and Lovozero massif, Russia, Ilimaussaq intrusion, Greenland) important mineral of agpaitic pegmatites and peralkaline fenites.[2]