Acetaldehyde (data page): Difference between revisions

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Template:Short description Template:Use dmy dates This page provides supplementary chemical data on acetaldehyde.

Material Safety Data Sheet

The handling of this chemical may require safety precautions. The directions on the Material Safety Datasheet (MSDS) should be followed.

Structure and properties

Template:Chembox header | Structure and properties
Index of refraction, nD 1.3392 at 18 °C
Abbe number ?
Dielectric constant, εr 21.1 ε0 at 21 °C
Bond strength ?
Bond length ?
Bond angle ?
Magnetic susceptibility ?
Surface tension[1] 22.3 dyn/cm at 10 °C
21.2 dyn/cm at 20 °C
17.0 dyn/cm at 50 °C
Viscosity[2] 0.2751 mPa·s at 0 °C
0.2521 mPa·s at 10 °C
0.2307 mPa·s at 20 °C

Thermodynamic properties

Template:Chembox header | Phase behavior
Triple point ? K (? °C), ? Pa
Critical point[3] 466 K (183 °C), 5570 kPa
Std enthalpy change
of fusion
, ΔfusHo
2.310 kJ/mol
Std entropy change
of fusion
, ΔfusSo
15.43 J/(mol·K)
Std enthalpy change
of vaporization
, ΔvapHo
26.12 kJ/mol
Std entropy change
of vaporization
, ΔvapSo
? J/(mol·K)
Template:Chembox header | Solid properties
Std enthalpy change
of formation
, ΔfHosolid
? kJ/mol
Standard molar entropy,
Sosolid
? J/(mol K)
Heat capacity, cp ? J/(mol K)
Template:Chembox header | Liquid properties
Std enthalpy change
of formation
, ΔfHoliquid
–196.4 kJ/mol
Standard molar entropy,
Soliquid
117.3 J/(mol K)
Enthalpy of combustion, ΔcHo –1167 kJ/mol
Heat capacity, cp 96.21 J/(mol K) at 0 °C
89.05 J/(mol K) at 25 °C
Template:Chembox header | Gas properties
Std enthalpy change
of formation
, ΔfHogas
–170.7 kJ/mol
Standard molar entropy,
Sogas
250.3 J/(mol K)
Heat capacity, cp 55.32 J/(mol K) at 25 °C

Vapor pressure of liquid

Template:Chembox header | P in mm Hg 1 10 40 100 400 760
Template:Chembox header | T in °C –81.5 –56.8 –37.8 –22.6 4.9 20.2

Table data obtained from CRC Handbook of Chemistry and Physics 44th ed.

log10 of Acetaldehyde vapor pressure. Uses formula: logePmmHg=loge(760101.325)18.27131loge(T+273.15)7241.251T+273.15+130.8048+2.633634×105(T+273.15)2 obtained from CHERIC[3]

Template:Clear

Spectral data

Template:Chembox header | UV-Vis
λmax ? nm
Extinction coefficient, ε ?
Template:Chembox header | IR
Major absorption bands[4]
(liquid film)
Wave number transmittance
3432 cm−1 72%
3001 cm−1 66%
2846 cm−1 42%
2733 cm−1 44%
1727 cm−1 4%
1629 cm−1 79%
1429 cm−1 36%
1401 cm−1 41%
1350 cm−1 25%
1179 cm−1 70%
1114 cm−1 29%
945 cm−1 77%
767 cm−1 61%
514 cm−1 35%
Template:Chembox header | NMR
Proton NMR  
Carbon-13 NMR  
Other NMR data  
Template:Chembox header | MS
Masses of
main fragments
 

References

  1. Lange's Handbook of Chemistry, 10th ed. pp. 1661–1663
  2. Lange's Handbook of Chemistry, 10th ed. pp. 1669–1674
  3. 3.0 3.1 Template:Cite web
  4. Template:Cite web

Template:Cite journal Template:Chemical data page general note