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{{Short description|A sudden increase in x-ray absorption}}
In [[X-ray absorption spectroscopy]], the '''K-edge''' is a sudden increase in x-ray absorption occurring when the [[photon energy|energy of the X-rays]] is just above the binding energy of the innermost [[electron shell]] of the [[atom]]s interacting with the photons. The term is based on [[X-ray notation]], where the innermost electron shell is known as the K-shell. Physically, this sudden increase in attenuation is caused by the [[photoelectric]] absorption of the photons. For this interaction to occur, the photons must have more energy than the binding energy of the K-shell electrons (K-edge). A photon having an energy just above the [[binding energy]] of the [[electron]] is therefore more likely to be absorbed than a photon having an energy just below this binding energy or significantly above it.<ref>{{Cite book|last1=Curry|first1=Thomas S.|url=https://books.google.com/books?id=W2PrMwHqXl0C|title=Christensen's Physics of Diagnostic Radiology|last2=Dowdey|first2=James E.|last3=Murry|first3=Robert C.|date=1990|publisher=Lippincott Williams & Wilkins|isbn=978-0-8121-1310-5|pages=78|language=en|chapter=Attenuation}}</ref>

The energies near the K-edge are also objects of study, and provide other information.

==Use==
The two [[radiocontrast]] agents [[iodine]] and [[barium]] have ideal K-shell binding energies for absorption of X-rays: 33.2&nbsp;keV and&nbsp;37.4 keV respectively, which is close to the mean energy of most diagnostic X-ray beams. Similar sudden increases in attenuation may also be found for other inner shells than the K shell; the general term for the phenomenon is [[absorption edge]].<ref>[http://physics.nist.gov/PhysRefData/XrayMassCoef/intro.html NIST data for full tabulation].</ref>

Dual-energy [[computed tomography]] techniques take advantage of the increased attenuation of iodinated radiocontrast at lower tube energies to heighten the degree of contrast between iodinated radiocontrast and other high attenuation biological material present in the body such as blood and hemorrhage.<ref>{{Cite web|url=https://www.ctisus.com/responsive/learning/pearls/neuroradiology/dual-energy|title = Neuroradiology: Dual Energy Imaging Pearls - Educational Tools &#124; CT Scanning &#124; CT Imaging &#124; CT Scan Protocols}}</ref>

==Metal K-edge==

Metal K-edge [[spectroscopy]] is a spectroscopic technique used to study the [[Electron configuration|electronic structures]] of [[transition metal]] atoms and [[Coordination complex|complexes]]. This method measures [[X-ray absorption spectroscopy|X-ray absorption]] caused by the [[Electron excitation|excitation]] of a 1s electron to valence bound states localized on the metal, which creates a characteristic absorption peak called the K-edge. The K-edge can be divided into the pre-edge region (comprising the pre-edge and rising edge transitions) and the near-edge region (comprising the intense edge transition and ~150&nbsp;eV above it).

=== Pre-edge ===
The K-edge of an [[open shell]] [[transition metal]] ion displays a weak pre-edge 1s-to-valence-metal-d transition at a lower energy than the intense edge jump. This dipole-forbidden transition gains intensity through a [[quadrupole]] mechanism and/or through 4p mixing into the final state. The pre-edge contains information about ligand fields and [[oxidation state]]. Higher oxidation of the metal leads to greater stabilization of the 1s orbital with respect to the metal d orbitals, resulting in higher energy of the pre-edge. Bonding interactions with [[ligand]]s also cause changes in the metal's [[effective nuclear charge]] (Z<sub>eff</sub>), leading to changes in the energy of the pre-edge.

The intensity under the pre-edge transition depends on the geometry around the absorbing metal and can be correlated to the structural symmetry in the molecule.<ref>{{cite journal | last1=Westre | first1=Tami E. | last2=Kennepohl | first2=Pierre | last3=DeWitt | first3=Jane G. | last4=Hedman | first4=Britt | last5=Hodgson | first5=Keith O. |author-link5=Keith Hodgson| last6=Solomon | first6=Edward I. |author-link6=Edward I. Solomon| title=A Multiplet Analysis of Fe K-Edge 1s → 3d Pre-Edge Features of Iron Complexes | journal=Journal of the American Chemical Society | publisher=American Chemical Society (ACS) | volume=119 | issue=27 | year=1997 | issn=0002-7863 | doi=10.1021/ja964352a | pages=6297–6314}}</ref> Molecules with [[centrosymmetry]] have low pre-edge intensity, whereas the intensity increases as the molecule moves away from centrosymmetry. This change is due to the higher mixing of the 4p with the 3d orbitals as the molecule loses centrosymmetry.

=== Rising-edge ===
A rising-edge follows the pre-edge, and may consist of several overlapping transitions that are hard to resolve. The energy position of the rising-edge contains information about the oxidation state of the metal. 

In the case of copper complexes, the rising-edge consists of intense transitions, which provide information about bonding. For Cu<sup>I</sup> species, this transition is a distinct shoulder and arises from intense electric-dipole-allowed 1s→4p transitions. The normalized intensity and energy of the rising-edge transitions in these Cu<sup>I</sup> complexes can be used to distinguish between two-, three- and four-coordinate Cu<sup>I</sup> sites.<ref>{{cite journal | last1=Kau | first1=Lung Shan | last2=Spira-Solomon | first2=Darlene J. | last3=Penner-Hahn | first3=James E. |author-link3=James Penner-Hahn| last4=Hodgson | first4=Keith O. |author-link4=Keith Hodgson| last5=Solomon | first5=Edward I. |author-link5=Edward I. Solomon| title=X-ray absorption edge determination of the oxidation state and coordination number of copper. Application to the type 3 site in Rhus vernicifera laccase and its reaction with oxygen | journal=Journal of the American Chemical Society | publisher=American Chemical Society (ACS) | volume=109 | issue=21 | year=1987 | issn=0002-7863 | doi=10.1021/ja00255a032 | pages=6433–6442}}</ref> In the case of higher-oxidation-state copper atoms, the 1s→4p transition lies higher in energy, mixed in with the near-edge region. However, an intense transition in the rising-edge region is observed for Cu<sup>III</sup> and some Cu<sup>II</sup> complexes from a formally forbidden two electron 1s→4p+shakedown transition. This “shakedown” process arises from a 1s→4p transition that leads to relaxation of the excited state, followed by a [[Charge-transfer complex#Ligand-to-metal charge transfer|ligand-to-metal charge transfer]] to the excited state.

This rising-edge transition can be fitted to a [[valence bond]] configuration (VBCI) model to obtain the composition of the [[ground state]] wavefunction and information on ground state [[covalency]]. The VBCI model describes the ground and excited state as a linear combination of the metal-based d-state and the ligand-based charge transfer state. The higher the contribution of the charge transfer state to the ground state, the higher is the ground state covalency indicating stronger metal-ligand bonding.

=== Near-edge ===
The near-edge region is difficult to quantitatively analyze because it describes transitions to continuum levels that are still under the influence of the core potential. This region is analogous to the [[EXAFS]] region and contains structural information. Extraction of metrical parameters from the edge region can be obtained by using the multiple-scattering code implemented in the MXAN software.<ref>{{cite journal | last1=Benfatto | first1=M. | last2=Della Longa | first2=S. | title=Geometrical fitting of experimental XANES spectra by a full multiple-scattering procedure | journal=Journal of Synchrotron Radiation | publisher=International Union of Crystallography (IUCr) | volume=8 | issue=4 | date=20 June 2001 | issn=0909-0495 | doi=10.1107/s0909049501006422 | pages=1087–1094| pmid=11486360 | doi-access=free }}</ref>

==Ligand K-edge==

Ligand K-edge [[spectroscopy]] is a spectroscopic technique used to study the [[Electron configuration|electronic structures]] of metal-ligand [[Coordination complex|complexes]].<ref>{{Cite journal| last1 = Solomon | first1 = E.| title = Ligand K-edge X-ray absorption spectroscopy: covalency of ligand–metal bonds| journal = Coordination Chemistry Reviews| volume = 249| pages = 97–129| year = 2005 | doi = 10.1016/j.ccr.2004.03.020| last2 = Hedman | first2 = B.| last3 = Hodgson | first3 = K.| last4 = Dey | first4 = A.| last5 = Szilagyi | first5 = R.| issue = 1–2}}</ref> This method measures [[X-ray absorption spectroscopy|X-ray absorption]] caused by the [[Electron excitation|excitation]] of ligand 1s electrons to unfilled p orbitals ([[principal quantum number]] <math>n \leq 4</math>) and continuum states, which creates a characteristic absorption feature called the K-edge.

=== Pre-edges ===
Transitions at energies lower than the edge can occur, provided they lead to orbitals with some ligand p character; these features are called pre-edges. Pre-edge intensities (''D''<sub>0</sub>) are related to the amount of ligand (L) character in the unfilled orbital:

:<math>D_0(L \ 1s \rightarrow \psi^*) = const \ \vert \langle L \ 1s \vert \mathbf{r} \vert \psi^* \rangle \vert^2 
= \alpha^2 \ const \ \vert \langle L \ 1s \vert \mathbf{r} \vert L \ np \rangle \vert^2 </math>

where <math>\psi^*</math> is the wavefunction of the unfilled orbital, '''r''' is the transition dipole operator, and <math>\alpha^2</math> is the "covalency" or ligand character in the orbital. Since <math>\psi^* = \sqrt{1-\alpha^2} \vert M_d \rangle - \alpha \vert L_{np} \rangle </math>, the above expression relating intensity and quantum transition operators can be simplified to use experimental values:

:<math> D_0 = \frac{\alpha^2 h}{3n}I_s</math>

where ''n'' is the number of absorbing ligand atoms, ''h'' is the number of holes, and ''I<sub>s</sub>'' is the transition dipole integral which can be determined experimentally. Therefore, by measuring the intensity of pre-edges, it is possible to experimentally determine the amount of ligand character in a molecular orbital.

== See also ==
* [[Metal L-edge]]
* [[Extended X-ray absorption fine structure]]

== References ==
{{reflist}}

{{X-ray science}}
[[Category:X-ray absorption spectroscopy]]
[[Category:X-rays]]